I can't recall if that can be done, but it doesn't sound familiar. I'll look later and update if I see anything like that.
UPDATE: There is a "Sync" config item that allows you to define a Local Folder and a corresponding pCloud Drive Folder. It looks like you can define a local folder, but then the 'pCloud folder' is any folder you have in your pCloud drive, existing or new. Could that be what you're looking for?
DCS is what I play most of the time - particularly the Viper. I help run the unit I play with as well.
Elite Dangerous is the only other sim I play.