[-] perestroika@slrpnk.net 3 points 3 days ago* (last edited 3 days ago)

Interesting article, thank you. :)

I wouldn't get one for myself because I have lots of big plants (hazel, cherry and sea-buckthorn), but it makes me wonder - why did some species of fungi start glowing? Did they do it by accident, for no good reason?

[-] perestroika@slrpnk.net 17 points 4 weeks ago* (last edited 4 weeks ago)

News of the sentencing reached the public broadcaster here in Estonia, including Dale Vince's comment that "this resembles Russia or maybe North Korea" and Chris Packham's assessment that "this is a threat against freedom of speech".

I hope the judgement gets overturned on appeal, and the law that enabled the judgement gets scrapped or rewritten.

I also suspect that the next people who want to stop traffic will not choose peaceful assembly as their method, but will use far more dangerous methods - sabotage from distance, e.g. no more traffic lights on a big intersection. Needless to say, state will cry "terrorism" then, and that is not a desirable outcome, so I hope nobody feels compelled to prove the point.

[-] perestroika@slrpnk.net 27 points 1 month ago

Knowing psychology, almost any PR advisor will advise to temporarily cease media attacks against a person who's been shot.

As a minimum, messages may need to be reworded, because Trump is likely to change his messaging after his narrow escape.

[-] perestroika@slrpnk.net 25 points 1 month ago* (last edited 1 month ago)

Some notes:

  • almost no doubt: this will have a mobilizing effect for Trump supporters ("our great leader is being attacked", etc)

  • possibly: this will improve Trump's ratings among voters with no clear political preference (a big story where he's not the villain is what he needs)

  • pattern: historically, surviving an assassination attempt has improved a candidate's chances of getting elected; in the most recent example, Slovakia's prime minister Fico enjoyed a boost in ratings while in hospital after being seriously wounded

I don't blame Democrats for temporarily ceasing campaign advertisement. Two principles dictate this: "you don't kick a person who is already down" (Trump was incredibly lucky and isn't) and "you don't attack someone who has martyrdom effect". Generally, you wait until the dust settles. Democrats too will wait until the dust settles. They will also check the popularity ratings and decide how to proceed.

In my opinion, Democrats would strongly benefit from a younger candidate. I would advise getting someone under 55 to run. Among the wider population, not enough people understand that, as things are, the Democratic candidate is Kamala Harris, her name is just currently Joe Biden. :o

Overall, it seems that Trump has considerable chances of getting elected president. Preventing that will require exceptional effort and considerable luck. Only if the Democrats manage to paint a clear picture of what a Trump presidential term would bring about, and only if that picture causes their voters to show up and vote nearly without exception - only then will things turn out differently.

My personal view from Eastern Europe - contingency plans for a Trump presidency ceasing aid to Ukraine have a very high probability of occurrence now (estimated time: early 2025). Over here, everyone and their cat will researching cheap weapons systems to replace things that only the US can provide. I think that group will now include myself.

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submitted 1 month ago* (last edited 1 month ago) by perestroika@slrpnk.net to c/science@slrpnk.net

In the article, researchers modeled the passage of the solar system through the galactic interstellar medium, components of which move at differing velocities and orbits.

They found that approximately 2-3 megayears ago, the solar system most likely entered a cloud of mainly cold hydrogen, and the density of the cloud was such that it should have considerably compressed the heliosphere (Sun's bubble of radiation and fields). Earth would have been outside the heliosphere either permanently or periodically. Currently the heliosphere ends far beyond the most distant planet, at approximately 130 Earth-Sun distances (astronomical units).

This would have greatly subdued the influence of solar wind on Earth, at the same time exposing the planet to interstellar cosmic rays. It is further speculated that studies which analyze Earth climate during the aforementioned period may benefit from accounting for this possibility.

Researchers sought confirmation for their model from geological records and found some, in the isotope content of iron and plutonium in sediments: iron 60 and plutonium 244 aren't produced by processes on Earth, so an influx would mean that solar wind no longer sufficed to beat back interstellar gas and dust (the latter containing radioisotopes from supernova explosions).

"By studying geological radioisotopes on Earth, we can learn about the past of the heliosphere. 60Fe is predominantly produced in supernova explosions and becomes trapped in interstellar dust grains. 60Fe has a half-life of 2.6 Myr, and 244Pu has a half-life of 80.7 Myr. 60Fe is not naturally produced on Earth, and so its presence is an indicator of supernova explosions within the last few (~10) million years. 244Pu is produced through the r-process that is thought to occur in neutron star mergers22. Evidence for the deposition of extraterrestrial 60Fe onto Earth has been found in deep-sea sediments and ferromanganese crusts between 1.7 and 3.2 Ma (refs. 23,24,25,26,27), in Antarctic snow [28] and in lunar samples [29]. The abundances were derived from new high-precision accelerator mass spectrometry measurements. The 244Pu/60Fe influx ratios are similar at ~2 Ma, and there is evidence of a second peak at ~7 Ma (refs. 23,24)."

[-] perestroika@slrpnk.net 20 points 2 months ago

Thanks for the news, but also - thanks for posting a proper summary. :)

(So many videos have only the YouTube-compiled summary, which is typically totally off topic.)

[-] perestroika@slrpnk.net 22 points 5 months ago* (last edited 5 months ago)

The car is correctly represented, about 0.15 KWh / km is what one gets.

However, the positioning of the e-bike looks strange to me. I've looked at previous studies and the e-biker has always been first in efficiency - because the efficiency of a motor far exceeds the efficiency of human digestion and muscles, while weight and speed remain comparable to an ordinary cyclist.

I think someone has calculated food energy incorrectly, or assumed that e-bikes move faster than they do. :)

[-] perestroika@slrpnk.net 17 points 7 months ago* (last edited 7 months ago)

I should add that, to my knowledge, there is no such rule in c/solarpunk. The rules are:

  • be constructive: there is no need of another internet space full of competition, negativity, rage etc.;
  • no bigotry, including racism, sexism, ableism, transphobia, homophobia or xenophobia;
  • be empathic: empathy is more rebellious than a middle finger;
  • no porn and no gore: let’s keep this place easy to manage;
  • no ads / spamming / flooding, we don’t want to buy/consume your commodified ideas;
  • occasional self-promotion by active members is fine.

Rules pertaining to talk about war, weapons, the military, weapons industry, agression vs. defense, imperialism vs. not conquering other lands, discussing history or politics, or staying strictly on topic - I don't see such rules.

I have the feeling that the rule was in the head of the moderator in question, which is not good at all - a moderator should stick to published rules.

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submitted 7 months ago* (last edited 7 months ago) by perestroika@slrpnk.net to c/meta@slrpnk.net

Background: yesterday, there was heated discussion in the thread "military-industrial complex is a supervillain of causing the climate crisis" (link).

Among others, the thread creator posted a comment to the Guardian article "The climate costs of war and militaries can no longer be ignored", commenting it thusly:

If you want more context or won’t take my word on how militarism will kill is all, you can read this article.

I replied, a copy of my reply is below for your judgement. My reply got moderated by someone with the reason "Comment does not address intent of original post and promotes weapons industry / war in Ukraine."

I think my comment both addressed the topic, did not promote the weapons industry but helping Ukraine defend itself (ironically, tools for military self-defense come from the weapons industry) and did not promote the war (in fact, I noted that war is expensive, resource-intensive and stupid), but did explain the dynamics of war and revolutions.

I consider this moderator misconduct, likely motivated by their political views - and have asked a server administrator to talk with the moderator involved, to ascertain if they can refrain from using moderator powers as a political club to hit people, or to secure their demotion from a moderating role.

The removed post, for your judgement:


The article is fine, and I second the recommendation to read it, but from the article to the slogan you present, things do not follow a logical path.

Yes, war is both an incredibly expensive activity (diverting money that could be used) and a resource-intensive activity (the money goes into actual materials that almost surely destroy something or get destroyed) and an incredibly stupid activity (and it can snowball)...

...but the problem is that successful unilateral disarmament during a war tends to result in a situation called "defeat". If the defeat is not an attack being defeated, but defense being defeated, that is called a "conquest". Now, letting a conquest succeed has a historical tendency of the conqueror having more experience at conquest, and more resources to conquer with... which has, several times in history, lead to another conquest or a whole series of conquests. A regional war in Ukraine resulting in Ukraine being taken over by Russia has a high probability of producing:

  1. a bigger regional war later, in which Russia, using its own resources and those of Ukraine, proceeds to another country, gets into a direct conflict with NATO and then indeed there is a risk of a global war
  1. an encouraging effect after which China, noting that international cooperation against the agressor was ultimately insufficient, and deeming itself better prepared than Russia, decides that it can take Taiwan with military force

However, a war ending with inability to show victory tends to produce a revolution in the invading country. For example, World War I produced a revolution in Russia and subsequently a revolution in Germany, with several smaller revolutions in between, empires collapsing and a brief bloom of democracy in Europe, before the Great Depression and the rise of fascism ate all the fruits. The Falklands War produced a revolution in Argentina. The Russo-Japanese war produced the 1905 near-revolution in Russia.

It is better for Ukraine to not get conquered. It is better for Russia to be unable to conquer Ukraine. That result is also better for everyone around them. It's even better globally because it sets a precedent of large-scale cooperation defeating an agressive superpower, discouraging agressive superpowers from undertaking similar wars until memory starts fading again.

Unfortunately, until we see indications that Russian society is getting ready to stop the war (this could involve starting negotiations on terms palatable to Ukraine, a change of leadership, a withdrawal, a revolution, etc)... the path to achieving that outcome remains wearing out the agressor: producing enough weapons and delivering them to Ukraine.

Ultimately, both sides in a war wear each other down. The soldiers most eager to fight are killed soonest. The people most unwilling to get mobilized or recruited, and soldiers most unwilling to fight - they remain alive. If they are pressed forever, some day they will make the calculation: there are less troops blocking the way home than in the trenches of the opposing side. After that realization, they eventually tend to mutiny. Invading troops tend to do that a bit easier than defending troops, because they sense less purpose in their activity. In the long run, if nothing else happens, that will happen. There is just (probably, regrettably) no particularly quick shortcut to getting there.

[-] perestroika@slrpnk.net 25 points 7 months ago* (last edited 7 months ago)

Strongly disagree.

Disarmament is feasible (and very smart, because war is a terrible waste) if the other side is understanding and willing. In the 1980-ties, the USSR under Gorbachev was willing to mutually reduce nuclear weapons. Gorbachev also ended the attempt to make Afghanistan into a Soviet satellite state and loosened the rules in the Soviet bloc enough for most of Eastern Europe to leave the bloc. Russia under Putin has not shown any willingness to widthdraw or disarm. In fact, it is making desperate attempts to restart all the Soviet military industries, double down and overwhelm Ukraine.

(for those unaware: the war is Gaza is statistically a gang shootout compared to the war in Ukraine, the intensity differs so much that I'm not even addressing it - it's practically over, Hamas attacked and lost)

NATO countries are of course increasing military production - ironically at such a leisurely pace that EU has been able to supply some 0.3 million of the 1 million shells promised to Ukraine, while North Korea has been able to hand 2 million shells to Russia. I don't see a case for claiming that NATO is arming too fast. I see a case for claiming that NATO is arming ridiculously slow, at a pace which might allow Russia to force an unfavourable deal on Ukraine.

I would predict: if Putin wins in Ukraine, or gets considerable parts of Ukraine as war spoils, in a decade's time, the next war will be Russia vs. Eastern Europe. Most of the warring parties will be NATO members then. And indeed, those countries (Finland, Estonia, Latvia, Lithuania, Poland, Czech Republic, Slovakia, Romania, Bulgaria) - they have all rapidly raised their military production and purchases.

About escalation: so far, all the long-range offensive weapons supplied by NATO have come with the strict condition that they may not be fired at Russian territory, and Ukraine has respected that - firing them only at occupied Ukrainian territory. Not a single ATACMS or Storm Shadow has landed in a Russian nuclear bunker, not to mention a seat of government. Ukraine is using Western missiles to shoot at its own (occupied) territory, hardly an escalation.

(a side note: Ukrainian-made drones do land in Russia regularly, mostly destroying aircraft that would bomb Ukraine - and World War 3 has not broken out because of that)

To finish up, I'd like to point out that the US is not even scheduled to give airplanes to Ukraine. The F-16 planes are being given by Denmark and the Netherlands.

P.S.

What's the rationale for calling Biden "Genocide Joe"? If that's an appropriate nickname, what do we call heads of state who start an actual war? :o

P.P.S.

Problems have differing levels of urgency. Wars tend to have the highest. Several EU countries have indeed been forced to scale back their climate plans because they don't have enough money to make the green transition and help Ukraine defend against Russia at the same time. The rise in interest rates has also contributed - it's harder to finance projects with a loan. However, they have also made incredibly fast pace at curbing their use of Russian oil and gas. Ironically, by proving what a fine seller Russia is ("run for the hills" grade of fine), Putin has contributed greatly to the transition off fossil fuels. Once he's deposed, tried and jailed, he should get a medal for that. :)

39
submitted 8 months ago by perestroika@slrpnk.net to c/fixing@slrpnk.net

This article is about fixing, but with a twist - it's about fixing trains that their manufacturer sabotaged. :D

In Poland, it took the hacker crew "Dragon Sector" months of work to find a software "time bomb" that was sabotaging "Impuls" trains manufactured by Newag, once their maintenance was handed over to another company.

Let this be a reminder to everyone about closed source technology and critical infrastructure.

[-] perestroika@slrpnk.net 27 points 8 months ago* (last edited 8 months ago)

It's actually a bit more complicated. :) They made vessels from copper when they could - copper is a superb heat conductor. But copper gets toxic fast when you cook acidic food. It gets worse if you don't clean your copper vessels. Wikipedia tells:

Copper is reactive with acidic foods which can result in corrosion, the byproducts of which can foment copper toxicity. In certain circumstances, however, unlined copper is recommended and safe, for instance in the preparation of meringue, where copper ions prompt proteins to denature (unfold) and enable stronger protein bonds across the sulfur contained in egg whites. Unlined copper is also used in the making of preserves, jams and jellies.

Despite not having adequate chemistry or medicine, people in old times had a clue - they saw that copper sometimes fouled and turned green, and suspected this was not good, preferring tin-lined copper vessels as the economical alternative to silver-lined copper vessels.

(Needless to say, industries of that time didn't produce stainless steel - maybe some alchemist blacksmith knew enough to make it, but it was not a thing.)

Lining copper pots and pans prevents copper from contact with acidic foods. The most popular lining types are tin, stainless steel, nickel and silver.

...but the chemistry of the time being what it was - shoddy - sometimes tin was contaminated with lead (Pb), sometimes it was deliberately adulterated with lead, and shit happened.

In the middle ages, guilds had a system of proof marks and inspectors to ensure craftsmen wouldn't add too much lead to tin alloys. The Nuremberg standard for example specified 1 part of lead against 10 parts of tin, but in Luzern, Switzerland, a problematic alloy was used.

As for Romans...

However, the use of leaden cookware, though popular, was not the general standard of use. Copper cookware was used far more generally and no indication exists as to how often sapa was added or in what quantity. (Grape syrup)

29
submitted 8 months ago* (last edited 8 months ago) by perestroika@slrpnk.net to c/offgrid@slrpnk.net

Living off grid often correlates with poorly accessible locations - because that's where the infrastructure is not.

On certain latitudes, especially near bodies of water, especially in remote locations - do not ask who the snow comes for - it always comes for you (and with a grudge). So, what ya gonna do?

Over here, a tractor being incomplete (it is great folly to go into winter with an incomplete tractor), snow is handled by an electric microcar. Since the microcar is made of thin sheet metal and plastic, it cannot carry a plow... but the rear axle being solid steel, it can pull one.

The plow is one year old, and was previously pulled by a gasoline car. It is made of construction steel: 8 mm L-profiles shaped like a letter A with double horizontal bars. The point of connection on top ensures it doesn't lift too much while plowing. It's currently fixed with an unprofessional and temporary C-clamp (there will be an U-bolt soon). It is pulled with a chain.

If snow is heavy, the L-profiles lift the plow on top of snow, and you have to plow the same road many times. Sometimes it veers off sideways. Generally, you have to catch the snow early with this system - if you're late, you're stuck. :)

Not many advantages, but dirt cheap. Don't go plowing public roads with such devices - it is nearly invisible to fellow drivers, and cops would get a seizure.

1
submitted 8 months ago* (last edited 8 months ago) by perestroika@slrpnk.net to c/science@slrpnk.net

Some Chinese researchers have found a new catalyst for electrochemically reducing CO2. Multiple such catalysts are known, but so far, only copper favours reaction products with a carbon chain of at least 2 carbons (e.g. ethanol).

The new catalyst requires a specific arrangement of tin atoms on tin disulphate substrate, seems to work in a solution of potassium hydrogen carbonate (read: low temperature) and is 80% specific to producing ethanol - a very practical chemical feedstock and fuel.

The new catalyst seems stable enough (97% activity after 100 hours). Reaction rates that I can interpret into "good" or "bad" aren't found - it could be slow to work. The original is paywalled, a more detailed article can be found at:

Carbon-Carbon Coupling on a Metal Non-metal Catalytic Pair

Overall, it's nice to see some research into breaking down CO2 for energy storage, but there is nothing practical (industrial) on that front yet, only lab work.

30
submitted 9 months ago* (last edited 9 months ago) by perestroika@slrpnk.net to c/offgrid@slrpnk.net

To make no excessive claims, I have to admit I burnt a fair bit of wood during the night. In the morning however, around 9 o'clock, the solar fence (nominal power 2400 W) was giving 600 W and steaming vigorously. By 10 o'clock, it had thawed and gave 940 W. Later, other panel arrays took over and wattage decreased. The energy was used to run a heat pump.

P.S. Knowing that server resources aren't infinite, I hosted the image externally, I hope that hosting on "postimages.org" works smoothly.

1
submitted 10 months ago* (last edited 10 months ago) by perestroika@slrpnk.net to c/abolition@slrpnk.net

The short war which Azerbaijan waged against Armenian-populated Karabakh after a months-long blocade is over (Armenian separatists lost, and will likely get ethnically cleansed out of the region)...

...but in the aftermath, it's worth pointing out that several high-profile Azeris did speak against their government starting a war - and were repressed.

The most worrisome case is the chairman of the confederation of trade unions, Afiaddin Mammadov. A provocateur who had previously injured himself threw a knife at him, and cops arrested him immediately after that, claiming he had injured the provocateur.

1
submitted 10 months ago* (last edited 10 months ago) by perestroika@slrpnk.net to c/science@slrpnk.net

To my knowledge, this is the second time a sample is returned from an asteroid to Earth - only preceded by Hayabusa-2 fetching a sample from asteroid Ryugu. The capsule has been found and the sample stabilized with nitrogen. Fetching the sample required 7 years, studying it will require a bit of time too.

It is too early to speculate whether interesting discoveries will follow, but Bennu is considered to be an interesting asteroid - likely not a break-up product, but something that represents the original composition of the solar system.

Bennu is also considered a hazardous space object, ranked high on the Palermo scale of impact risk and kinetic yield, so knowing what it's made of can be practically worthwhile.

More information here:

https://en.wikipedia.org/wiki/OSIRIS-REx

1
submitted 11 months ago by perestroika@slrpnk.net to c/science@slrpnk.net

The inverse vaccine, described in Nature Biomedical Engineering, takes advantage of how the liver naturally marks molecules from broken-down cells with “do not attack” flags to prevent autoimmune reactions to cells that die by natural processes.

PME researchers coupled an antigen — a molecule being attacked by the immune system— with a molecule resembling a fragment of an aged cell that the liver would recognize as friend, rather than foe. The team showed how the vaccine could successfully stop the autoimmune reaction associated with a multiple-sclerosis-like disease.

[-] perestroika@slrpnk.net 23 points 1 year ago* (last edited 1 year ago)

...and that is why Chat cannot be trusted to build houses. It hallucinates:

Exhibit A:

At its core, this building incorporates an innovative vertical farming system. Towering gardens thrive within its walls,

Exhibit B:

The building’s walls are constructed using rammed earth or compressed earth blocks, utilizing the surrounding soil and natural resources abundantly available in the area.

One can go vertical, or one can go rammed earth. One does not go vertical with rammed earth. :) And wind turbines attached to building structure are a nuisance. An efficient turbine needs to be clear of obstacles.

Beyond that, it has done a good job. The write-up was streamlined with my cultural sensibilities, before it collided head on with my sense of engineering. :)

[-] perestroika@slrpnk.net 39 points 1 year ago* (last edited 1 year ago)

More information can be found here: https://veilid.com/framework

I read it, haven't tested it - commentary below.

Before I go into commentary, I will summarize: my background is from I2P - I helped build bits and pieces of that network a decade ago. As far as I can tell, Veilid deals in concepts that are considerably similar to I2P. If the makers have implemented things well, it could be a capable tool for many occasions. :) My own interest in recent years has shifted towards things like Briar. With that project, there is less common ground. Veilid is when you use public infrastructure to communicate securely, with anonymity. Briar is when you bring your own infrastructure.

  • Networking

Looks like I2P, but I2P is coded in Java only. Veilid seems to have newer and more diverse languages (more capability, but likely more maintenance needs in future). I2P has a lot of legacy attached by now, and is not known for achieving great performance. A superficial reading of the network protocol doesn't enable me to tell if Veilid will do better - I can only tell that they have thought of the same problems and found their own solutions. I would hope that when measured in a realistic situation, Veilid would exceed the performance of I2P. How to find out? By trying, in masses and droves...

  • Cryptography

Impressive list of ciphers. Times have changed, I'm not qualified to say anything about any of them. It leaves the appearance that these people know what they are doing, and are familiar with recent developments in cryptography. They also seem to know that times will change ("Veilid has ensured that upgrading to newer cryptosystems is streamlined and minimally invasive to app developers, and handled transparently at the node level."), which is good. Keeping local storage encrypted is an improvement over I2P - last time I worked with I2P, an I2P router required external protection (e.g. Linux disk encryption) against seizing the hardware. With mobile devices ever-present everywhere, storage encryption is a reasonable addition. I notice that the BlockStore functionality is not implemented yet. If they intend to get it working, storage encryption is a must, of course.

  • RPC (remote procedure calls)

Their choice of a procedure call system is unfamiliar to me, but I read about it. I didn't find anything to complain about.

  • DHT (distributed hash table)

Looks somewhat like I2P.

  • Private routing

Looks very much like I2P.

1
submitted 1 year ago* (last edited 1 year ago) by perestroika@slrpnk.net to c/science@slrpnk.net

Most people would typically think than smelling a scent (unless it's a powerful poison or medicament) won't change much in a person's health... but apparently, a variation in the scent environment has effect on the human brain, especially if the person is already old and their senses are degrading. It has also been observed that viral infections damaging a person's olfactory nerves result in changes to the brain - with less input, the neural networks involved with scent tend to atrophy. Coinidentally, some neural networks involved with scent recognition are also involved with memory.

Prios studies already support the idea that training one's sense of smell helps older people avoid cognitive deterioration. This study brings highly significant statistical results and adds one bit - wakefulness is not required to benefit. Apparently, the stimulation a person receives from feeling different scents bypasses sleep (or maybe, even improves the quality of sleep).

126

Long story made short: apparently, the previous administration didn't really try (since it was Bolsonaro's, I am not surprised). EU import controls and financial interventions have also helped:

He believes the slowdown is due to a combination of factors: the resumption of embargoes and other protection activities by the government, improved technical analysis that reveal where problems are occurring more quickly and in more detail, greater involvement by banks to deny credit to landowners involved in clearing trees, and also wariness among farmers generated by the European Union’s new laws on deforestation-free trade. It may be no coincidence that deforestation has not fallen as impressively in the cerrado savanna, which is not yet covered by the EU’s controls.

1
submitted 1 year ago* (last edited 1 year ago) by perestroika@slrpnk.net to c/science@slrpnk.net

Superconductivity is a condition of matter where resistance to electrical current disappears.

The first superconductors needed cooling to near the absolute zero. The next generation worked at temperatures of liquid nitrogen. A room-temperature atmospheric-pressure superconductor is a highly sought after material (e.g. it would expand possibilities to hande plasma for fusion research and make MRI machines easier to build).

A substance named LK-99 has recently caused interest in the research community. Its a copper-enriched lead apatite, typically made by reacting lead sulphate with copper phosphide. It is speculated to be superconductive at room temperature.

It is also thought that interesting properties are not inherent to the substance, but a particular kind of crystal lattice which this subtance obtains - if produced in certain ways.

The name LK-99 refers to Sukbae Lee and Ji-Hoon Kim, and the number refers to 1999, when these Korean researchers first stumbled upon it.

Studies back then were interrupted. They weren't certain of its properties and it was hard to make repeatably. When a researcher named Tong-Shik Choi died in 2017, he requested in his will that research into LK-99 be continued. The resources were found and his request was granted.

Then, other factors intervened, among them COVID. The first article was rejected by Nature because an extraordinary claim requires extraordinary proof. An article in Arxiv (not peer reviewed) at the end of July 2023 drew international attention, however.

Many persons and teams started attempting to replicate the experimental results. The process is still half way through, but considerable progress has been made.

  • Beijing University, school of material science + Beihang university: the experiment was made, but the effect could not be reproduced (they obtained a paramagnetic semiconductor of little interest)

  • Huazhong University, center for crystalline materials and micro/nanodevices: they obtained a diamagnetic crystal with interesting properties (repelled by a ferromagnet regardless of orientation, a property which a superconductor must have, but which is also shared by non-superconductive diamagnets)

  • National Physics Laboratory of India: failed to replicate the effect

  • Professor Sun Yue, South-Eastern University of China: got a weak diamagnetic crystal

  • Iris Alexandra (from Russia, plant physiologist): with an alternative production method, obtained a tiny but strongly diamagnetic crystal

  • Sinéad Griffin (Lawrence Berkley National Laboratory, from the US): published an article, attempting to theoretically explain how superconductivity might arise in the substance, explanatory tweet here

  • Junwen Lai (Shenyang National Material Science Laboratory, China): published an article about the electron structure of the substance, without opinion regarding superconductivity, with the opinion that gold doping would be better than copper doping

So, strong evidence is absent until now - we may have much merriness about nothing. There is a bunch of hypothesis and enough material to fit on a fingertip. :)

Background:

https://en.wikipedia.org/wiki/LK-99

[-] perestroika@slrpnk.net 49 points 1 year ago* (last edited 1 year ago)

This is such a puzzle, thank you. :)

I checked Sci-Hub - no matches for "proton battery", neither for "hydrogen flow battery".

Falling back on chemistry - I recalled that "dissolving a concentrated acid in water should be done with care". It is exothermic, water may suddenly boil and splash acid all over the careless chemist.

By definition, acids are substances that can easily give protons (hydrogen ions) to other chemicals. A classic reaction would be acid + base = salt + water (acid gives the H and base gives the OH, so we get H2O), the other components of the acid and base form the salt.

If there is only water on the other side, I thought "the reaction is acid giving protons to water". Which acid? How many protons? Those questions might determine the amount of power available. And of course - how to control the reaction and extract electrical power? Browsing Wikipedia, I came across two pages: protonation and deprotonation and a sample reaction with sulphuric acid, but found no reference to electricity production, though potential / voltage is obviously available when ions are being created and transfered.

Then, finally I found the RMIT press release, and understood that acid is not a central participant of this reaction:

https://www.rmit.edu.au/news/all-news/2018/mar/all-power-to-the-proton

Some pickings:

The working prototype proton battery uses a carbon electrode as a hydrogen store, coupled with a reversible fuel cell to produce electricity.

It’s the carbon electrode plus protons from water that give the proton battery it’s environmental, energy and potential economic edge, says lead researcher Professor John Andrews.

During charging, the carbon in the electrode bonds with protons generated by splitting water with the help of electrons from the power supply. The protons are released again and pass back through the reversible fuel cell to form water with oxygen from air to generate power. Unlike fossil fuels, the carbon does not burn or cause emissions in the process.

The researchers’ experiments showed that their small proton battery, with an active inside surface area of only 5.5 square centimetres (smaller than a 20 cent coin), was already able to store as much energy per unit mass as commercially-available lithium ion batteries. This was before the battery had been optimised.

“Future work will now focus on further improving performance and energy density through use of atomically-thin layered carbon-based materials such as graphene, with the target of a proton battery that is truly competitive with lithium ion batteries firmly in sight,” Andrews said.

There is a photo of the three scientists with a cell and multimeter, and the meter reads 1.1559 volts, so we know the cell voltage is low, but not impractically low. A link to a scientific article and a description of the cell follows:

"Technical feasibility of a proton battery with an activated carbon electrode"

The latest version combines a carbon electrode for solid-state storage of hydrogen with a reversible fuel cell to provide an integrated rechargeable unit.

During charging, protons produced by water splitting in a reversible fuel cell are conducted through the cell membrane and directly bond with the storage material with the aid of electrons supplied by the applied voltage, without forming hydrogen gas.

(this implies that overcharging results in hydrogen formation, like in lead acid batteries - the solution is to have it vented typically)

In electricity supply mode this process is reversed; hydrogen atoms are released from the storage and lose an electron to become protons once again. These protons then pass back through the cell membrane where they combine with oxygen and electrons from the external circuit to re-form water.

(this leads to the question of oxygen availability on the other side, and how to ensure it's adequate - gases are a nuisance due to their low density, but water can dissolve only so much oxygen, and this could limit the power output or storage capacity of the cell, however, if one built a flow battery, a redundantly large mass of water could be used to supply oxygen - but I'd really like to know if they used gaseous or dissolved oxygen)

Therefore, in the proton battery, many processes in the conventional hydrogen-based energy storage system that cause energy losses and irreversible entropy increases are omitted, such as hydrogen gas evolution and compression, and the splitting of molecular hydrogen into protons in fuel cell mode.

A summary of the scientific paper:

The experimental results reported here show that a small proton battery (active area 5.5 cm2) with a porous activated carbon electrode made from phenolic resin and 10 wt% PTFE binder was able to store in electrolysis (charge) mode very nearly 1 wt% hydrogen, and release on discharge 0.8 wt% in fuel cell (electricity supply) mode. A significant design innovation is the use of a small volume of liquid acid within the porous electrode to conduct protons (as hydronium) to and from the nafion membrane of the reversible cell. Hydrogen gas evolution during charging of the activated carbon electrode was found to be very low until a voltage of around 1.8 V was reached. Future work is being directed towards increasing current densities during charging and discharging, multiple cycle testing, and gaining an improved understanding of the reactions between hydronium and carbon surfaces.

So, the acid was not a reaction participant, but a proton conductor.

If anyone has a copy of the paper, please share - it seems like it would be interesting. :)

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perestroika

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