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By itself nicotine is less harmful and physically addictive than caffeine. It's really not far from caffeine in mental addiction either, but it's short elimination halflife doesn't do it any favors.
I make my own eliquid, so I don't have to worry about the health risks of flavors, and vegetable glycerin and propylene glycol safe to inhale (I use temperature control to prevent the coil from getting hot enough to degrade the VG)