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Natural leather is durable and lasting and where its used can be repaired, unlike artificial leather.
If a cow has to be killed due to people wanting its meat, why waste its hide instead of using it? The poluter here is the meat industry. Not leather production. To turn hide into leather one can use chemicals yes, but natural tanning is still used widely.
In a perfect world lether can also come from animals that have died of natural causes.
Plastic leather also wears out so quickly. Real leather is much stronger and easier to repair/restore.
As the person highlighted (and you have expanded on), there are a lot of ethical and sustainability problems with the leather industry as it is, but I think it'd be far better to improve the problems with natural leather than to expect much from the plastic leather
They make vege leather nowadays, I think. Never got my hands on anything made of it because it was so expensive, though.
You've got to keep in mind that everyone doesn't feel the same. I personally feel gross having anything to do with leather because I can't shake the feeling it's a corpse's skin. It would be the same to me if it was a dead human's skin.
I'm not asking for understanding on how I feel, but more just understanding that maybe natural leather is the best option for most people right now in terms of environmental impact - but it's important we develop other solutions too and try to make them more environmentally over time, because not everyone is the same.